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| Genre/Form: | Electronic books Textbooks |
|---|---|
| Additional Physical Format: | Print version: Blackman, Allan (Allan G.). Chemistry. Milton, Qld. : John Wiley & Sons Australia, Ltd, 2016 (OCoLC)903004834 |
| Material Type: | Document, Internet resource |
| Document Type: | Internet Resource, Computer File |
| All Authors / Contributors: |
Allan Blackman |
| ISBN: | 9780730328353 073032835X |
| OCLC Number: | 967841417 |
| Notes: | Includes index. |
| Description: | 1 online resource (xx, 1159 pages) : color illustrations |
| Contents: | 1 The atom -- 1.1 Atoms, molecules, ions, elements and compounds -- 1.2 The atomic theory -- 1.3 The structure of the atom -- Chemical Connections Imaging atoms -- Atomic mass -- Chemical Connections Saving lives with isotopes -- 1.4 The periodic table of the elements -- The modern periodic table -- Naming the elements -- 1.5 Electrons in atoms -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 2 The language of chemistry -- 2.1 Measurement -- SI units -- Non-SI units -- Dimensional analysis -- Precision and accuracy -- Uncertainties and significant figures -- Chemical Connections The National Measurement Institute -- 2.2 Representations of molecules and reactions -- Chemical formulae -- Structural formulae -- Three-dimensional structures -- Mechanistic arrows in chemical reactions -- 2.3 Nomenclature -- Chemical Connections IUPAC -- Naming inorganic compounds -- Naming organic compounds -- Chemical Connections Bosutnib -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- Maths for chemistry -- 3 Chemical reactions and stoichiometry -- 3.1 Chemical equations -- Specifying states of matter -- 3.2 Balancing chemical equations -- 3.3 The mole -- 3.4 Empirical formulae -- Chemical Connections Elemental analysis at the Campbell Microanalytical Laboratory -- Mole ratios from chemical formulae -- Determination of chemical formulae -- Determination of empirical formulae -- 3.5 Stoichiometry, limiting reagents and percentage yield -- Mole ratios in chemical reactions -- Limiting reagents -- Percentage yield -- 3.6 Solution stoichiometry -- The concentration of solutions. Applications of solution stoichiometry -- Stoichiometry of solutions containing ions -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 4 Atomic energy levels -- 4.1 Characteristics of atoms -- 4.2 Characteristics of light -- Wave-like properties of light -- Particle properties of light -- Chemical Connections The Australian Synchrotron -- Absorption and emission spectra -- Atomic spectra -- Quantisation of energy -- Energy level diagrams -- 4.3 Properties of electrons -- The Heisenberg uncertainty principle -- 4.4 Quantisation and quantum numbers -- Principal quantum number (n) -- Azimuthal quantum number (l) -- Magnetic quantum number (ml) -- Spin quantum number (ms) -- The Pauli exclusion principle -- 4.5 Atomic orbital electron distributions and energies -- Orbital electron distributions -- Orbital energies -- 4.6 Structure of the periodic table -- The Aufbau principle and order of orbital filling -- Valence electrons -- 4.7 Electron configurations -- Electron-electron repulsion -- Orbitals with nearly equal energies -- Configurations of ions -- Magnetic properties of atoms -- Excited states -- 4.8 Periodicity of atomic properties -- Atomic radii -- Ionisation energy -- Electron affinity -- Sizes of ions -- 4.9 Ions and chemical periodicity -- Cation stability -- Anion stability -- Metals, nonmetals and metalloids -- s-block elements -- p-block elements -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 5 Chemical bonding and molecular structure -- 5.1 Fundamentals of bonding -- The hydrogen molecule -- Bond length and bond energy -- Other diatomic molecules: F2 -- Unequal electron sharing -- Chemical Connections Electromagnetic radiation and cancer -- 5.2 Ionic bonding -- 5.3 Lewis structures. The conventions -- Building Lewis structures -- Resonance structures -- 5.4 Valence-shell-electron-pair repulsion (VSEPR) theory -- Two sets of electron pairs: linear geometry -- Three sets of electron pairs: trigonal planar geometry -- Four sets of electron pairs: tetrahedral geometry -- Five sets of electron pairs: trigonal bipyramidal geometry -- Six sets of electron pairs: octahedral geometry -- 5.5 Properties of covalent bonds -- Dipole moments -- Bond length -- Bond energy -- Chemical Connections Making use of the energy stored in covalent bonds -- Summary of molecular shapes -- 5.6 Valence bond theory -- Orbital overlap -- Conventions of the orbital overlap model -- Hybridisation of atomic orbitals -- Multiple bonds -- 5.7 Molecular orbital theory: diatomic molecules -- Molecular orbitals of H2 and He2 -- Molecular orbitals of O2 -- Homonuclear diatomic molecules -- Heteronuclear diatomic molecules -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 6 Gases -- 6.1 The states of matter -- 6.2 Describing gases -- Pressure (p) -- The gas laws -- The ideal gas equation -- 6.3 Molecular view of gases -- Molecular speeds -- Speed and energy -- Average kinetic energy and temperature -- Rates of gas movement -- Ideal gases -- 6.4 Gas mixtures -- Dalton's law of partial pressures -- Describing gas mixtures -- 6.5 Applications of the ideal gas equation -- Determination of molar mass -- Determination of gas density -- 6.6 Gas stoichiometry -- Summary of mole conversions -- 6.7 Real gases -- The halogens -- Properties of real gases -- The van der Waals equation -- Melting and boiling points -- 6.8 Intermolecular forces -- Dispersion forces -- Dipolar forces -- Hydrogen bonds -- Binary hydrogen compounds -- Chemical Connections Atmospheric carbon dioxide -- Summary. Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 7 Condensed phases: liquids and solids -- 7.1 Liquids -- Properties of liquids -- Vapour pressure -- 7.2 Solids -- Magnitudes of forces -- Molecular solids -- Network solids -- Metallic solids -- Ionic solids -- 7.3 Phase changes -- Phase diagrams -- Chemical Connections Chemistry and cool jackets -- 7.4 Order in solids -- Close-packed structures -- The crystal lattice and the unit cell -- Cubic structures -- Ionic solids -- 7.5 X-ray diffraction -- 7.6 Amorphous solids -- 7.7 Crystal imperfections -- 7.8 Modern ceramics -- Properties of ceramics -- Applications of advanced ceramics -- High-temperature superconductors -- Chemical Connections Fast trains on superconductors -- Summary -- Key concepts and equations -- Key terms -- Review questions -- Review problems -- Additional exercises -- 8 Chemical thermodynamics -- 8.1 Introduction to chemical thermodynamics -- 8.2 Thermodynamic concepts -- Heat and temperature -- System, surroundings and universe -- Units -- (SE (BX: the change in X -- State functions -- (SE (BG and spontaneity -- 8.3 The first law of thermodynamics -- Heat capacity and specific heat -- Determination of heat -- 8.4 Enthalpy -- Standard enthalpy of reaction -- Chemical Connections Cold fusion -- a nuclear reaction at room temperature -- Hess's law -- Standard enthalpy of formation -- Standard enthalpy of combustion -- Bond enthalpies -- Chemical Connections The thermodynamics of steam burns -- 8.5 Entropy -- Entropy and probability -- Entropy and entropy change -- Factors that affect entropy -- 8.6 The second law of thermodynamics -- 8.7 The third law of thermodynamics -- Chemical Connections Airconditioning and the second law of thermodynamics -- 8.8 Gibbs energy and reaction spontaneity -- The sign of (SE (BG -- Standard Gibbs energy change. |
| Responsibility: | Allan Blackman [and ten others]. |
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